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The Shocker



Real Name: Herman Schultz
First Appearance: Along Came Spidey
 
Escaping from prison with a serious mad on for Spider-Man for putting him there in the first place, The Shocker attempted to make as much destruction as possible in hopes of getting Spider-Man’s attention, even injuring Aunt May in the process.

A rejuvenated Spider-Man and his Amazing Friends later defeated him.